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• W2074968729 endingPage "2242" @default.
• W2074968729 startingPage "2240" @default.
• W2074968729 abstract "The ring-opening reaction of (S)-1-phenylspiro[2,4]hepta-4,6-diene with LiPPh2 proceeds with full regio- and stereoselectivity, taking place at phenyl-substituted carbon and with complete inversion of the configuration at the stereogenic center, yielding (S)-[Li(C5H4CH2CHPhPPh2)]. Optically active complexes of rhenium, rhodium, zirconium, and iron with this new chiral bidentate ligand have been prepared; additionally, the X-ray crystal structure of (S)-[Rh(η2-C2H4)(η5-C5H4CH2CHPhPPh2-κP)] is reported." @default.
• W2074968729 created "2016-06-24" @default.
• W2074968729 creator A5007308411 @default.
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• W2074968729 date "2000-05-11" @default.
• W2074968729 modified "2023-10-12" @default.
• W2074968729 title "Regio- and Stereoselective Ring-Opening Reactions of Chiral Substituted Spiro[2.4]hepta-4,6-dienes: A New, Simple, and Versatile Approach to the Synthesis of Optically Active Bidentate Cyclopentadienyl−Phosphine Ligands. X-ray Crystal Structure of (<i>S</i>)-[Rh(η²-C₂H₄)(η⁵-C₅H₄CH₂CHPhPPh₂-κ<i>P</i>)]" @default.
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• W2074968729 doi "https://doi.org/10.1021/om0001826" @default.
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