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- W2075026783 endingPage "2260" @default.
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- W2075026783 abstract "Homoallylic alcohols (primary, secondary, or tertiary containing an endocyclic or an exocyclic double bond) react with equimolar amounts of aldehydes (aliphatic or aromatic) and ketones (aliphatic) in the presence of 5 mol % of iodine. This Prins cyclization was used in the preparation of hexahydrobenzo[f]isochromenes and of a 4-hydroxy-tetrahydropyran, in 54–81% yield. The procedure is also efficient for an aza-Prins cyclization of a homoallylic sulfonamide and benzaldehyde, producing a hexahydrobenzo[f]isoquinoline." @default.
- W2075026783 created "2016-06-24" @default.
- W2075026783 creator A5050172683 @default.
- W2075026783 creator A5081232643 @default.
- W2075026783 date "2009-05-01" @default.
- W2075026783 modified "2023-09-24" @default.
- W2075026783 title "An expeditious synthesis of hexahydrobenzo[f]isochromenes and of hexahydrobenzo[f]isoquinoline via iodine-catalyzed Prins and aza-Prins cyclization" @default.
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- W2075026783 doi "https://doi.org/10.1016/j.tetlet.2009.02.202" @default.
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