FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2075039718> ?p ?o ?g. }

• W2075039718 endingPage "31" @default.
• W2075039718 startingPage "26" @default.
• W2075039718 abstract "Acylation reactions of naringin with palmitic acid were performed by a lipase after formation of highly concentrated homogeneous solutions. Their initial naringin concentration was 840–950 mM, which is 20–60 times greater than that in organic solvent media. The overall productivity of highly concentrated solutions was more than 15 times greater than those of organic phase media. The addition of DMSO (20–40%, w/w) to substrate mixtures lowered the melting temperature of a naringin–palmitic acid mixture (1:1 molar ratio) to about 40 °C. Reactions at 80 °C apparently followed Michaelis–Menten kinetics despite extremely high substrate concentrations. As the temperature increased from 60 °C to 80 °C, the apparent viscosity of the highly concentrated solution decreased remarkably from 4.31 Pa s to 0.063 Pa s. An activation energy of 7.65 kcal/mol obtained in a range of 60–75 °C suggests a diffusion-control. On the other hand, an activation energy of 17.09 kcal/mol in a range of 75–90 °C indicates a reaction-control. The highest product conversion yield of 33% (mol/mol) was obtained in a 10 h reaction at 80 °C. Addition of activated molecular sieves to the highly concentrated solution increased the product conversion yield by 7% (mol/mol), suggesting that the original equilibrium was disrupted by removing water and then a new equilibrium was reached." @default.
• W2075039718 created "2016-06-24" @default.
• W2075039718 creator A5050370216 @default.
• W2075039718 creator A5051331380 @default.
• W2075039718 creator A5073384154 @default.
• W2075039718 creator A5075340229 @default.
• W2075039718 date "2007-05-01" @default.
• W2075039718 modified "2023-10-18" @default.
• W2075039718 title "Lipase-catalyzed acylation of naringin with palmitic acid in highly concentrated homogeneous solutions" @default.
• W2075039718 cites W150196455 @default.
• W2075039718 cites W1964994058 @default.
• W2075039718 cites W1967897649 @default.
• W2075039718 cites W1971040583 @default.
• W2075039718 cites W1971518199 @default.
• W2075039718 cites W1980355904 @default.
• W2075039718 cites W1988827239 @default.
• W2075039718 cites W1989305095 @default.
• W2075039718 cites W1993114691 @default.
• W2075039718 cites W1995422905 @default.
• W2075039718 cites W2005095213 @default.
• W2075039718 cites W2010251382 @default.
• W2075039718 cites W2010807769 @default.
• W2075039718 cites W2011046260 @default.
• W2075039718 cites W2013720213 @default.
• W2075039718 cites W2014964154 @default.
• W2075039718 cites W2020200667 @default.
• W2075039718 cites W2030795605 @default.
• W2075039718 cites W2035176560 @default.
• W2075039718 cites W2046127687 @default.
• W2075039718 cites W2049599903 @default.
• W2075039718 cites W2054513432 @default.
• W2075039718 cites W2071109986 @default.
• W2075039718 cites W2071964836 @default.
• W2075039718 cites W2082921434 @default.
• W2075039718 cites W2084417500 @default.
• W2075039718 cites W2101426626 @default.
• W2075039718 cites W2140138726 @default.
• W2075039718 cites W2145553632 @default.
• W2075039718 cites W4242045016 @default.
• W2075039718 cites W44777472 @default.
• W2075039718 doi "https://doi.org/10.1016/j.molcatb.2007.02.002" @default.
• W2075039718 hasPublicationYear "2007" @default.
• W2075039718 type Work @default.
• W2075039718 sameAs 2075039718 @default.
• W2075039718 citedByCount "15" @default.
• W2075039718 countsByYear W20750397182012 @default.
• W2075039718 countsByYear W20750397182013 @default.
• W2075039718 countsByYear W20750397182014 @default.
• W2075039718 countsByYear W20750397182016 @default.
• W2075039718 countsByYear W20750397182017 @default.
• W2075039718 countsByYear W20750397182018 @default.
• W2075039718 countsByYear W20750397182019 @default.
• W2075039718 countsByYear W20750397182020 @default.
• W2075039718 countsByYear W20750397182023 @default.
• W2075039718 crossrefType "journal-article" @default.
• W2075039718 hasAuthorship W2075039718A5050370216 @default.
• W2075039718 hasAuthorship W2075039718A5051331380 @default.
• W2075039718 hasAuthorship W2075039718A5073384154 @default.
• W2075039718 hasAuthorship W2075039718A5075340229 @default.
• W2075039718 hasConcept C111368507 @default.
• W2075039718 hasConcept C121332964 @default.
• W2075039718 hasConcept C127313418 @default.
• W2075039718 hasConcept C134121241 @default.
• W2075039718 hasConcept C13965031 @default.
• W2075039718 hasConcept C161790260 @default.
• W2075039718 hasConcept C178790620 @default.
• W2075039718 hasConcept C181199279 @default.
• W2075039718 hasConcept C185592680 @default.
• W2075039718 hasConcept C193557335 @default.
• W2075039718 hasConcept C2777289219 @default.
• W2075039718 hasConcept C2777335409 @default.
• W2075039718 hasConcept C2779697368 @default.
• W2075039718 hasConcept C2779936771 @default.
• W2075039718 hasConcept C43617362 @default.
• W2075039718 hasConcept C543025807 @default.
• W2075039718 hasConcept C95121573 @default.
• W2075039718 hasConcept C97355855 @default.
• W2075039718 hasConceptScore W2075039718C111368507 @default.
• W2075039718 hasConceptScore W2075039718C121332964 @default.
• W2075039718 hasConceptScore W2075039718C127313418 @default.
• W2075039718 hasConceptScore W2075039718C134121241 @default.
• W2075039718 hasConceptScore W2075039718C13965031 @default.
• W2075039718 hasConceptScore W2075039718C161790260 @default.
• W2075039718 hasConceptScore W2075039718C178790620 @default.
• W2075039718 hasConceptScore W2075039718C181199279 @default.
• W2075039718 hasConceptScore W2075039718C185592680 @default.
• W2075039718 hasConceptScore W2075039718C193557335 @default.
• W2075039718 hasConceptScore W2075039718C2777289219 @default.
• W2075039718 hasConceptScore W2075039718C2777335409 @default.
• W2075039718 hasConceptScore W2075039718C2779697368 @default.
• W2075039718 hasConceptScore W2075039718C2779936771 @default.
• W2075039718 hasConceptScore W2075039718C43617362 @default.
• W2075039718 hasConceptScore W2075039718C543025807 @default.
• W2075039718 hasConceptScore W2075039718C95121573 @default.
• W2075039718 hasConceptScore W2075039718C97355855 @default.
• W2075039718 hasIssue "1-4" @default.
• W2075039718 hasLocation W20750397181 @default.
• W2075039718 hasOpenAccess W2075039718 @default.

• next