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- W2075058184 abstract "Publisher Summary This chapter describes the basis of dipolar nuclear magnetic resonance (NMR) experiments. Dipolar NMR experiments on solids have been discussed in two excellent monographs in solid-state NMR by Mehring and Fyfe. The chapter presents a brief summary of the essential theoretical background, and dipolar couplings in homonuclear spin pairs and heteronuclear spin pairs are also discussed. The applications described in the chapter vary from obtaining the fundamental structural information, such as bond lengths, identifying small molecules on surfaces, describing the conformation of peptides in membranes, characterizing magnetic shielding tensors, J coupling tensors, and, in some cases, nuclear quadrupolar coupling tensors. These latter parameters are of great interest, especially with the development of ever-improving theoretical calculations. Theoreticians must have reliable experimental data, with which to test their calculations and theoretical models. The sensitivity of the solid-state NMR experiment to internuclear separations, electronic environments and molecular motions has made it a useful and powerful probe of microscopic structure and it can be expected to provide even more detailed and exciting information in the future." @default.
- W2075058184 created "2016-06-24" @default.
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- W2075058184 date "2010-08-20" @default.
- W2075058184 modified "2023-09-26" @default.
- W2075058184 title "ChemInform Abstract: NMR Studies of Isolated Spin Pairs in the Solid State" @default.
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- W2075058184 doi "https://doi.org/10.1002/chin.199315339" @default.
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