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• W2075109230 abstract "Ferroelectricity in an organic charge-transfer compound, tetrathiafulvalene-$p$-chloranil (TTF-CA), originating from the one-dimensional valence and lattice instabilities, has been investigated by an electroreflectance (ER) method. Microscopic ER spectroscopy in the visible region enables real-space observations of both ferroelectric domain structures with a few hundred micrometers in size and depinning of the domain walls under strong electric fields. In addition, from ER spectroscopy in the infrared molecular-vibration region, we demonstrate that field-induced changes in the dimeric molecular displacement as well as charge transfer between TTF and CA molecules play an important role in the large dielectric response in TTF-CA." @default.
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• W2075109230 date "2009-11-06" @default.
• W2075109230 modified "2023-10-01" @default.
• W2075109230 title "Ferroelectric nature and real-space observations of domain motions in the organic charge-transfer compound tetrathiafulvalene-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>p</mml:mi></mml:math>-chloranil" @default.
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• W2075109230 doi "https://doi.org/10.1103/physrevb.80.205201" @default.
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