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• W2075147204 abstract "We report a highly permeable poly(ethylene oxide) (PEO)/silver nanoparticles (AgNPs)/p-benzoquinone (p-BQ) composite for use in a facilitated olefin transport membrane. Surface-tuned AgNPs were generated using AgBF4 as a precursor. The electronic structure of the AgNP surface was tuned by the electron acceptor p-BQ to induce positive charges. The interaction between olefins and the polarized surface of AgNPs in a permeable PEO matrix was expected to show excellent separation performance. Our results show that the PEO/AgNPs/p-BQ composite membranes possess a selectivity of 10 and a mixed-gas permeance of 15 GPU for durations longer than 240 h. The surface-activated AgNPs were characterized using UV-visible and X-ray photoelectron spectroscopies." @default.
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• W2075147204 date "2014-01-01" @default.
• W2075147204 modified "2023-10-18" @default.
• W2075147204 title "Highly permeable poly(ethylene oxide) with silver nanoparticles for facilitated olefin transport" @default.
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• W2075147204 doi "https://doi.org/10.1039/c3ra46506c" @default.
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