FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2075156520> ?p ?o ?g. }

• W2075156520 endingPage "150" @default.
• W2075156520 startingPage "141" @default.
• W2075156520 abstract "The chemisorption and thermal decomposition of ethyl iodide on Pt(111) have been studied by reflection-absorption infrared spectroscopy (RAIRS). At 100 K the chemisorption is molecular, and a change in adsorption geometry occurs from a flat to an upright orientation as the surface coverage is increased. Ethyl, ethylene and ethylidyne were identified at higher temperatures by IR spectrometry as decomposition products. As a consequence of the coverage-dependent orientation of the ethyl iodide molecules on the surface, different reaction mechanisms are operative at low and high coverages. At low coverages, ethyl iodide decomposes quantitatively between 150 and 200 K through a C-I bond breaking step followed by immediate dehydrogenation to ethylene. At saturation coverages, some ethylene formation competes with molecular desorption around 200 K (analogous to the low coverage decomposition), but additional ethylene is produced between 200 and 240 K in a slower, reversible reaction which involves the formation of ethyl species as stable intermediates. Ethylene further decomposes around 300 K to form ethylidyne." @default.
• W2075156520 created "2016-06-24" @default.
• W2075156520 creator A5074539493 @default.
• W2075156520 creator A5080547491 @default.
• W2075156520 creator A5083839366 @default.
• W2075156520 date "1992-02-01" @default.
• W2075156520 modified "2023-09-25" @default.
• W2075156520 title "A RAIRS study on the surface chemistry of ethyl iodide on Pt(111)" @default.
• W2075156520 cites W1507491839 @default.
• W2075156520 cites W1609531615 @default.
• W2075156520 cites W1965233419 @default.
• W2075156520 cites W1965426310 @default.
• W2075156520 cites W1978162450 @default.
• W2075156520 cites W1982363727 @default.
• W2075156520 cites W1983013479 @default.
• W2075156520 cites W1991321936 @default.
• W2075156520 cites W1997995459 @default.
• W2075156520 cites W2009034769 @default.
• W2075156520 cites W2011764801 @default.
• W2075156520 cites W2013065711 @default.
• W2075156520 cites W2016576270 @default.
• W2075156520 cites W2027904261 @default.
• W2075156520 cites W2032888181 @default.
• W2075156520 cites W2047472250 @default.
• W2075156520 cites W2057026947 @default.
• W2075156520 cites W2059400198 @default.
• W2075156520 cites W2076747673 @default.
• W2075156520 cites W2077663958 @default.
• W2075156520 cites W2081385617 @default.
• W2075156520 cites W2083579701 @default.
• W2075156520 cites W2084431367 @default.
• W2075156520 cites W2095531934 @default.
• W2075156520 cites W4234051899 @default.
• W2075156520 cites W4250518040 @default.
• W2075156520 doi "https://doi.org/10.1016/0039-6028(92)90466-j" @default.
• W2075156520 hasPublicationYear "1992" @default.
• W2075156520 type Work @default.
• W2075156520 sameAs 2075156520 @default.
• W2075156520 citedByCount "95" @default.
• W2075156520 countsByYear W20751565202012 @default.
• W2075156520 countsByYear W20751565202013 @default.
• W2075156520 countsByYear W20751565202014 @default.
• W2075156520 countsByYear W20751565202016 @default.
• W2075156520 countsByYear W20751565202017 @default.
• W2075156520 countsByYear W20751565202018 @default.
• W2075156520 countsByYear W20751565202019 @default.
• W2075156520 countsByYear W20751565202020 @default.
• W2075156520 countsByYear W20751565202022 @default.
• W2075156520 crossrefType "journal-article" @default.
• W2075156520 hasAuthorship W2075156520A5074539493 @default.
• W2075156520 hasAuthorship W2075156520A5080547491 @default.
• W2075156520 hasAuthorship W2075156520A5083839366 @default.
• W2075156520 hasConcept C119889771 @default.
• W2075156520 hasConcept C124681953 @default.
• W2075156520 hasConcept C126661725 @default.
• W2075156520 hasConcept C147789679 @default.
• W2075156520 hasConcept C150394285 @default.
• W2075156520 hasConcept C153642686 @default.
• W2075156520 hasConcept C160434732 @default.
• W2075156520 hasConcept C161790260 @default.
• W2075156520 hasConcept C162711632 @default.
• W2075156520 hasConcept C178790620 @default.
• W2075156520 hasConcept C179104552 @default.
• W2075156520 hasConcept C185592680 @default.
• W2075156520 hasConcept C2778597550 @default.
• W2075156520 hasConcept C2778870691 @default.
• W2075156520 hasConcept C2780059344 @default.
• W2075156520 hasConcept C2780073701 @default.
• W2075156520 hasConcept C2781059571 @default.
• W2075156520 hasConcept C32909587 @default.
• W2075156520 hasConcept C33790079 @default.
• W2075156520 hasConcept C75473681 @default.
• W2075156520 hasConceptScore W2075156520C119889771 @default.
• W2075156520 hasConceptScore W2075156520C124681953 @default.
• W2075156520 hasConceptScore W2075156520C126661725 @default.
• W2075156520 hasConceptScore W2075156520C147789679 @default.
• W2075156520 hasConceptScore W2075156520C150394285 @default.
• W2075156520 hasConceptScore W2075156520C153642686 @default.
• W2075156520 hasConceptScore W2075156520C160434732 @default.
• W2075156520 hasConceptScore W2075156520C161790260 @default.
• W2075156520 hasConceptScore W2075156520C162711632 @default.
• W2075156520 hasConceptScore W2075156520C178790620 @default.
• W2075156520 hasConceptScore W2075156520C179104552 @default.
• W2075156520 hasConceptScore W2075156520C185592680 @default.
• W2075156520 hasConceptScore W2075156520C2778597550 @default.
• W2075156520 hasConceptScore W2075156520C2778870691 @default.
• W2075156520 hasConceptScore W2075156520C2780059344 @default.
• W2075156520 hasConceptScore W2075156520C2780073701 @default.
• W2075156520 hasConceptScore W2075156520C2781059571 @default.
• W2075156520 hasConceptScore W2075156520C32909587 @default.
• W2075156520 hasConceptScore W2075156520C33790079 @default.
• W2075156520 hasConceptScore W2075156520C75473681 @default.
• W2075156520 hasIssue "1-2" @default.
• W2075156520 hasLocation W20751565201 @default.
• W2075156520 hasOpenAccess W2075156520 @default.
• W2075156520 hasPrimaryLocation W20751565201 @default.
• W2075156520 hasRelatedWork W1985315299 @default.
• W2075156520 hasRelatedWork W2013065711 @default.

• next