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- W2075199157 abstract "Rotationally resolved laser-induced fluorescence excitation spectra of the S1 ← S0 transitions have been recorded for various conformers of 1,3-diphenylpropane (DPP) in supersonic free expansion. Ab initio simulation of the rotational band contours, based on the S0 rotational constants from 6-31G(d) MP2 and transition moments from 6-31G(d) CI singles calculations, provides definitive assignments of the four major spectral features to particular torsional isomers. These assignments provide rational explanations for the conformation-dependent excimer formation in jet-cooled DPP." @default.
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- W2075199157 date "2000-01-21" @default.
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- W2075199157 title "Conformational Geometries and Conformation-Dependent Photophysics of Jet-Cooled 1,3-Diphenylpropane" @default.
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- W2075199157 doi "https://doi.org/10.1021/jp993647i" @default.
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