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- W2075230480 abstract "Abstract With a view to investigating the surface tensions of a (non-alkane+perfluoroalkane) mixture which, in a similar fashion to a typical (alkane+perfluoroalkane) mixture, displays large positive derivations from bulk ideality and large negative deviations from surface ideality, we have determined the orthobaric (gas + liquid) surface tension of tetrachloromethane at temperatures from 296 K to 323 K, and of (tetrachloromethane + tetradecafluoromethylcyclohexane) fromT= 303 K toT= 315 K close to the upper critical solution temperatureTUCS= 302.23 K. The surface tensions of the mixture display both large negative deviations from surface ideality and a close-to-horizontal inflection like that first predicted by Widom for the tension of the noncritical interface of a mixture at a critical end point. Incidentally, but no less interestingly, the mixture comprises substances of almost equal vapour pressure—and hence is neither normal nor non-normal in the sense of the Widom definition whereby a normal mixture is one in which the more volatile component is of lower surface tension, or tautness. It is surprising, therefore that the near-critical surface tension isotherms display an inflection of a nature more to be expected if the vapour pressures of the components were more different and tetradecafluoromethylcyclohexane were the more volatile." @default.
- W2075230480 created "2016-06-24" @default.
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- W2075230480 date "1996-07-01" @default.
- W2075230480 modified "2023-09-27" @default.
- W2075230480 title "Orthobaric surface tension of (tetrachloromethane + tetradecafluoromethylcyclohexane) in the critical region at temperatures fromT= 303 K toT= 315 K" @default.
- W2075230480 doi "https://doi.org/10.1006/jcht.1996.0070" @default.
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