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• W2075241561 startingPage "1765" @default.
• W2075241561 abstract "An unexpected C-F bond-cleavage reaction of unactivated fluoroalkanes with the well-known Grignard reagents without using metal catalysts has been discovered. For example, a reaction between 1-fluorooctane and phenyl magnesium chloride gave n-octylbenzene in moderate yield. This coupling reaction via the activation of an unactivated alkyl carbon-fluorine bond proceeds with phenylmagnesium chloride, whereas methylmagnesium chloride did not give the C-C cross-coupling product but rather a halogen exchange product." @default.
• W2075241561 created "2016-06-24" @default.
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• W2075241561 date "2009-03-12" @default.
• W2075241561 modified "2023-10-03" @default.
• W2075241561 title "C−F Bond-Cleavage Reactions of Fluoroalkanes with Magnesium Reagents and without Metal Catalysts" @default.
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• W2075241561 doi "https://doi.org/10.1021/ol900208n" @default.
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