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- W2075250865 abstract "Reaction of TsiLi (Tsi = (Me 3 Si) 3 C) with ( p -MeOC 6 H 4 ) 2 SiF 2 gave TsiSi(C 6 H 4 OMe- p ) 2 F, which was treated with LiAlH 4 to give (Me 3 Si) 3 CSi(C 6 H 4 OMe- p ) 2 H. Treatment of the latter with ICl in the presence of a large excess of Me 3 SiC 6 H 4 OMe- p gave (Me 3 Si) 3 CSi(C 6 H 4 OMe- p ) 2 Cl rather than the expected (Me 3 Si) 3 CSi(C 6 H 4 OMe- p ) 2 I. Use of Br 2 in place of ICl gave (Me 3 Si) 3 CSi(C 6 H 4 OMe- p ) 2 Br. The fluoride (Me 3 Si) 3 CSi(C 6 H 4 OMe- p ) 2 F was found to react with NaOMe/MeOH and NaOEt/EtOH, to give (Me 3 Si) 2 CHSi(C 6 H 4 OMe- p ) 2 OMe and (Me 3 Si) 2 CHSi(C 6 H 4 OMe- p ) 2 OEt, respectively, and secondary products formed from them. Only secondary products were observed from the corresponding (prolonged) reactions in NaOPr i /Pr i OH, and KOBu t /Bu t OH. The diol ( p -MeOC 6 H 4 ) 2 Si(OH) 2 was made by hydrolysis of ( p -MeOC 6 H 4 ) 2 SiCl 2 ." @default.
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- W2075250865 date "1997-01-01" @default.
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- W2075250865 title "Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4OMe-p)2X" @default.
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- W2075250865 doi "https://doi.org/10.1016/s0022-328x(97)00302-1" @default.
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