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• W2075313634 abstract "The rotational spectrum of a new isomer of OCS-CO(2) has been measured between 5 and 18 GHz using Fourier transform microwave spectroscopy. Both a- and b-type transitions of the parent dimer and the (13)CO(2)-containing isotopologue were fit and the resulting spectroscopic constants confirm that this is the planar O-interior, not-quite-as-parallel isomer that was experimentally observed for the first time in the recent infrared investigation of Dehghany et al. [J. Chem. Phys. 130, 224310 (2009)]. As in the infrared study, the microwave transitions of this isomer appear stronger than those of the previously reported lower energy isomer of OCS-CO(2) when helium is used as the backing gas for the supersonic expansion." @default.
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• W2075313634 date "2009-07-22" @default.
• W2075313634 modified "2023-10-18" @default.
• W2075313634 title "Fourier transform microwave spectra of a “new” isomer of OCS-CO2" @default.
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• W2075313634 doi "https://doi.org/10.1063/1.3186756" @default.
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