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- W2075314820 abstract "Abstract The standard molar Gibbs energy of formation of BaMoO 4 (s) has been determined by measuring e.m.f. of the cell: Pt/BaMoO 3 (s)+BaMoO 4 (s))/CSZ/air ( p (O 2 )=21.21 kPa)/Pt where CSZ represents 15 mol% CaO stabilized zirconia. E.m.f. measurements were carried out in the temperature range 1091 to 1309 K and its dependence on temperature could be represented by: E (V)±0.001=1.482−3.600×10 −4 T (K). Using the Gibbs energy data on BaMoO 3 (s) from our previous study along with the above e.m.f. data, the Δ f G m o ( T ) for BaMoO 4 (s) was calculated to be: Δ f G o m ( BaMoO 4 , s , T)( kJ mol −1 )±4.7=−1542.0+0.3552T( K ) Δ f H m o (298.15 K) is calculated by the second-law method using the relevant heat capacity data and the variation of Δ f G m o (BaMoO 4 , s, T ) with temperature and the value is −(1557.5±3.6) kJ mol −1 . The third-law values of Δ f H m o (298.15 K) at each experimental temperature were also calculated from free enthalpy functions −{( G o ( T )− H o (298.15 K))/ T } reported in the literature. The mean Δ f H m o (298.15 K) value by this method is −(1536.8±5.2) kJ mol −1 ." @default.
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- W2075314820 date "1998-02-01" @default.
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- W2075314820 title "Thermochemical studies on BaMoO4(s)" @default.
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- W2075314820 doi "https://doi.org/10.1016/s0925-8388(97)00458-1" @default.
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