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• W2075342885 endingPage "1374" @default.
• W2075342885 startingPage "1368" @default.
• W2075342885 abstract "Several octasubstituted zinc azaphthalocyanines (ZnAzaPcs) of the tetrapyrazinoporphyrazine type have been synthesized as potential sensitizers for photodynamic therapy (PDT). Octasubstituted complexes, with thiophen-2-yl, thiophen-3-yl or benzo[b]thiophen-3-yl peripheral groups, were synthesized and characterized. Octa(thiophen-2-yl) ZnAzaPc is a better singlet oxygen producer and has a red shifted UV absorption Q-band compared to both thiophen-3-yl and benzo[b]thiophen-3-yl substituted ZnAzaPcs. Thus, the thiophen-2-yl substituent is better suited for our purpose. Unsymmetrically substituted ZnAzaPcs were synthesized by cyclotetramerisations of pyrazine-2,3-dicarbonitriles attached to one thiophen-2-yl group and one alkylsulfanyl, thiomorpholinyl or imide group. Constitutional isomers were detected by NMR spectroscopy for some of these complexes. Compared to unsubstituted ZnAzaPc, red shifted Q-bands were observed for all these complexes, due to the presence of thiophen-2-yl groups. The least promising complexes are ZnAzaPcs with thiomorpholine or imide peripheral substituents, i.e. where the peripheral substituents are attached to the macrocycle through nitrogen atoms. Low singlet oxygen quantum yields (ΦΔ) and also low fluorescence quantum yields (ΦF) were observed for these ZnAzaPcs. In the case of combined thiophen-2-yl and alkylsulfanyl substituents, the values of ΦΔ were the highest and reached values of approximately 0.69." @default.
• W2075342885 created "2016-06-24" @default.
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• W2075342885 date "2008-04-01" @default.
• W2075342885 modified "2023-10-17" @default.
• W2075342885 title "Syntheses of octasubstituted zinc azaphthalocyanines with thiophene or thiophene combined with sulfanyl, amino or imido substituents: Influence of the substituents on photochemical and photophysical properties" @default.
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• W2075342885 doi "https://doi.org/10.1016/j.poly.2008.01.015" @default.
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