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• W2075359904 abstract "A new annulation method is presented, involving a boron trifluoride catalysed Michael addition of trialkylsilyl enol ethers to methyl vinyl ketone (MVK) in the presence of a hydroxylic compound. This methodology allows regiospecific 3-oxobutylation of either of the two isomeric enol ethers of mono or di-substituted cyclanones. Octalones 2d, e and hydrindenones 17 with the two alkyl groups in a cis relationship can thus be specifically obtained. This method has been applied to a short and efficient preparation of (±)-dehydrofukinone 10." @default.
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• W2075359904 date "1992-01-01" @default.
• W2075359904 modified "2023-09-25" @default.
• W2075359904 title "Lewis acid catalysed Michael-type addition. A new regio- and diastereo-selective annulation method using methyl vinyl ketone" @default.
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• W2075359904 doi "https://doi.org/10.1039/p19920000387" @default.
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