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• W2075376969 abstract "14N chemical shifts for compounds of types Download : Download full-size image are reported as well as a collection of 14N NMR data of selected alkyl-, stannyl-, germyl-, and plumbylamines for comparison. The strong +I effect of the trimethylsilyl group is shown by δ(14N) when X acts as an inductive electron-withdrawing substituent. If mesomeric effects of X must be considered, δ(14N) indicates participation of the free electron pair at nitrogen attached to silicon in π bonding or in an extension of the π-electron system. Silicon-nitrogen(dp) π bonding accounts, at least partly, for the δ(14N) value of N-trimethylsilylpyrrol." @default.
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• W2075376969 date "1978-09-01" @default.
• W2075376969 modified "2023-09-25" @default.
• W2075376969 title "14N NMR studies on some trimethylsilylamine derivatives" @default.
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• W2075376969 doi "https://doi.org/10.1016/s0022-2364(78)80002-x" @default.
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