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- W2075555832 abstract "Abstract Approximate cumulative reaction probabilities have been calculated from two empirical rate equations: one is the 3-parameter rate equation, ATnexp(−E/kBT), and the other is the modified Arrhenius equation, A ′ exp (−E 0 /k B T 2 +T 0 2 ) proposed in Chem. Phys. Lett. 160 (1989) 295, for expressing the rate constants at low temperatures. Numerical calculations were made for the D + H2 → DH + H reaction. It is shown that this reaction occurs mainly through tunneling at 200 K, and that the 3-parameter rate equation involves the tunneling effect along with the correction at high temperatures." @default.
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- W2075555832 date "2004-04-01" @default.
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- W2075555832 title "Cumulative reaction probability N(E) as estimated from empirical bimolecular rate constant k(T)" @default.
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- W2075555832 doi "https://doi.org/10.1016/j.cplett.2004.01.117" @default.
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