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- W2075557502 abstract "The prochiral polypyrazolylborate complexes [RB(3,5-X2-pz)3]Mo(CO)2(NO) (R = pz, X = H; R = H, X = CH3), react with the optically active aminophosphines L = (C6H5)2PNR′CH(CH3)(C6H5) (R′= H, CH3), to give the monosubstitution products [RB(3,5-X2-pz)3]Mo(CO)(NO)L, in which the metal atom is a new chiral center. The separation of the diastereoisomers, differing only in the Mo configuration, by preparative liquid chromatography and fractional crystallization is described, their CD and 1H NMR spectra and their reactivities are discussed and compared with those of the cyclopentadienyl analogues." @default.
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- W2075557502 date "1982-12-01" @default.
- W2075557502 modified "2023-10-18" @default.
- W2075557502 title "Optically active polypyrazolylborate molybdenum complexes with aminophosphines as chiral ligands" @default.
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- W2075557502 doi "https://doi.org/10.1016/s0022-328x(00)85139-6" @default.
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