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- W2075597619 abstract "Abstract A kinetic study of the reaction between PdCl2−4 and isoprene is described. The results are interpreted in terms of the formation of two π-complexes between palladium(II) and isoprene, one having only one double bond coordinated to the metal, the other being a chelated diene compound. Nucleophilic attack of solvent methanol on these intermediate complexes gives the methoxy π-allyl complex." @default.
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- W2075597619 date "1974-01-01" @default.
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- W2075597619 title "The mechanism of formation of π-allyl complexes: The reaction of PdCl2−4 with isoprene in methanol" @default.
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- W2075597619 doi "https://doi.org/10.1016/s0022-328x(00)92189-2" @default.
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