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- W2075632478 abstract "The size of the chelate ring determines the reactivity of Nbv complexes: Whereas [Ph4P][Nb(SCH2CH2S)3] is completely stable in acetonitrile, in the case of the homologous title complex a reductive dimerization takes place. The anion 1 formed initially reacts further with methanol to give 2, which was isolated as the Ph4P-salt; the structure of this anion is shown on the right." @default.
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- W2075632478 date "1989-01-01" @default.
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- W2075632478 title "Self-Reduction of [Ph4P][Nb(SCH2CH2CH2S)3] with Formation of a Nb2IV Complex" @default.
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- W2075632478 doi "https://doi.org/10.1002/anie.198900981" @default.
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