Matches in SemOpenAlex for { <https://semopenalex.org/work/W2075687112> ?p ?o ?g. }
- W2075687112 endingPage "698" @default.
- W2075687112 startingPage "694" @default.
- W2075687112 abstract "The etherolysis/condensation of TiCl4 by diisopropyl ether (iPr2O) as well as the direct condensation between TiCl4 and Ti(OiPr)4 are efficient nonhydrolytic sol−gel routes to titania. A comparison of the solution chemistry of the two routes was performed by means of NMR spectroscopy. In both cases the condensation is slow at room temperature; the true precursors are titanium chloroisopropoxides in equilibrium through fast ligand-exchange reactions. The condensation takes place at 100 °C after an induction period which drastically depends upon the OiPr/Ti ratio in the reaction mixture. This behavior is related to the composition of the starting chloroisopropoxides mixture. The key species in the induction process appears to be Ti(OiPr)Cl3, which catalyzes the first condensation reactions." @default.
- W2075687112 created "2016-06-24" @default.
- W2075687112 creator A5008477925 @default.
- W2075687112 creator A5012872546 @default.
- W2075687112 creator A5036526617 @default.
- W2075687112 creator A5059969550 @default.
- W2075687112 creator A5078163332 @default.
- W2075687112 date "1997-03-01" @default.
- W2075687112 modified "2023-10-07" @default.
- W2075687112 title "A Solution Chemistry Study of Nonhydrolytic Sol−Gel Routes to Titania" @default.
- W2075687112 cites W1988521481 @default.
- W2075687112 cites W1998170765 @default.
- W2075687112 cites W2006053209 @default.
- W2075687112 cites W2021623869 @default.
- W2075687112 cites W2023746791 @default.
- W2075687112 cites W2024195788 @default.
- W2075687112 cites W2037491455 @default.
- W2075687112 cites W2046681172 @default.
- W2075687112 cites W2089460689 @default.
- W2075687112 cites W2146700364 @default.
- W2075687112 cites W2147418416 @default.
- W2075687112 cites W2312322544 @default.
- W2075687112 cites W2317464468 @default.
- W2075687112 cites W2318294232 @default.
- W2075687112 cites W36521839 @default.
- W2075687112 cites W4250517443 @default.
- W2075687112 doi "https://doi.org/10.1021/cm960337t" @default.
- W2075687112 hasPublicationYear "1997" @default.
- W2075687112 type Work @default.
- W2075687112 sameAs 2075687112 @default.
- W2075687112 citedByCount "138" @default.
- W2075687112 countsByYear W20756871122012 @default.
- W2075687112 countsByYear W20756871122013 @default.
- W2075687112 countsByYear W20756871122014 @default.
- W2075687112 countsByYear W20756871122015 @default.
- W2075687112 countsByYear W20756871122016 @default.
- W2075687112 countsByYear W20756871122017 @default.
- W2075687112 countsByYear W20756871122018 @default.
- W2075687112 countsByYear W20756871122019 @default.
- W2075687112 countsByYear W20756871122020 @default.
- W2075687112 countsByYear W20756871122021 @default.
- W2075687112 countsByYear W20756871122022 @default.
- W2075687112 countsByYear W20756871122023 @default.
- W2075687112 crossrefType "journal-article" @default.
- W2075687112 hasAuthorship W2075687112A5008477925 @default.
- W2075687112 hasAuthorship W2075687112A5012872546 @default.
- W2075687112 hasAuthorship W2075687112A5036526617 @default.
- W2075687112 hasAuthorship W2075687112A5059969550 @default.
- W2075687112 hasAuthorship W2075687112A5078163332 @default.
- W2075687112 hasConcept C116569031 @default.
- W2075687112 hasConcept C121332964 @default.
- W2075687112 hasConcept C127413603 @default.
- W2075687112 hasConcept C161790260 @default.
- W2075687112 hasConcept C170493617 @default.
- W2075687112 hasConcept C178790620 @default.
- W2075687112 hasConcept C179104552 @default.
- W2075687112 hasConcept C185592680 @default.
- W2075687112 hasConcept C188027245 @default.
- W2075687112 hasConcept C200093464 @default.
- W2075687112 hasConcept C207245611 @default.
- W2075687112 hasConcept C2781126881 @default.
- W2075687112 hasConcept C38398224 @default.
- W2075687112 hasConcept C42360764 @default.
- W2075687112 hasConcept C506065880 @default.
- W2075687112 hasConcept C55493867 @default.
- W2075687112 hasConcept C97355855 @default.
- W2075687112 hasConceptScore W2075687112C116569031 @default.
- W2075687112 hasConceptScore W2075687112C121332964 @default.
- W2075687112 hasConceptScore W2075687112C127413603 @default.
- W2075687112 hasConceptScore W2075687112C161790260 @default.
- W2075687112 hasConceptScore W2075687112C170493617 @default.
- W2075687112 hasConceptScore W2075687112C178790620 @default.
- W2075687112 hasConceptScore W2075687112C179104552 @default.
- W2075687112 hasConceptScore W2075687112C185592680 @default.
- W2075687112 hasConceptScore W2075687112C188027245 @default.
- W2075687112 hasConceptScore W2075687112C200093464 @default.
- W2075687112 hasConceptScore W2075687112C207245611 @default.
- W2075687112 hasConceptScore W2075687112C2781126881 @default.
- W2075687112 hasConceptScore W2075687112C38398224 @default.
- W2075687112 hasConceptScore W2075687112C42360764 @default.
- W2075687112 hasConceptScore W2075687112C506065880 @default.
- W2075687112 hasConceptScore W2075687112C55493867 @default.
- W2075687112 hasConceptScore W2075687112C97355855 @default.
- W2075687112 hasIssue "3" @default.
- W2075687112 hasLocation W20756871121 @default.
- W2075687112 hasOpenAccess W2075687112 @default.
- W2075687112 hasPrimaryLocation W20756871121 @default.
- W2075687112 hasRelatedWork W1989101040 @default.
- W2075687112 hasRelatedWork W2022547337 @default.
- W2075687112 hasRelatedWork W2129098726 @default.
- W2075687112 hasRelatedWork W2320868797 @default.
- W2075687112 hasRelatedWork W2358532565 @default.
- W2075687112 hasRelatedWork W2808522196 @default.
- W2075687112 hasRelatedWork W3006371521 @default.
- W2075687112 hasRelatedWork W3168498822 @default.
- W2075687112 hasRelatedWork W4310117701 @default.
- W2075687112 hasRelatedWork W630597580 @default.
- W2075687112 hasVolume "9" @default.