FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2075703752> ?p ?o ?g. }

• W2075703752 endingPage "4514" @default.
• W2075703752 startingPage "4509" @default.
• W2075703752 abstract "Expectation values of various operators with respect to nonrelativistic, self-consistent-field wave functions of good quality for 46 diatomic molecules are computed to examine the differences between the relativistic kinetic energy 〈Hr〉 and the quasirelativistic kinetic energy 〈Tnr〉+〈Hmv〉 in which 〈Tnr〉 is the nonrelativistic kinetic energy and 〈Hmv〉 is the mass–velocity correction. Then 〈Hrc〉=〈Hr〉−〈Tnr〉=〈H mv〉+〈δE〉 is the full relativistic correction to the kinetic energy. 〈Hrc〉 can differ appreciably from 〈Hmv〉 for molecules containing at least one atom with a moderately large atomic number Z. These differences are greatly amplified when the relativistic corrections to dissociation energies are considered; the mass–velocity contribution to the binding energy is found to be inaccurate even for moderate values of Z. Great care is necessary to ensure that the molecular and atomic calculations are of comparable accuracy. A qualitative argument is provided to explain why 〈Hmv〉 can provide a reasonable approximation to 〈Hrc〉 for small enough Z despite the fact that the two operators are inequivalent for αp≥1 where α is the fine structure constant and p is the momentum. Finally the asymptotic behavior of the pertinent integrands is used to show why the numerical evaluation, in momentum space, of 〈Hrc〉 is easier than that of 〈Hmv〉." @default.
• W2075703752 created "2016-06-24" @default.
• W2075703752 creator A5051630394 @default.
• W2075703752 date "1986-10-15" @default.
• W2075703752 modified "2023-10-16" @default.
• W2075703752 title "Relativistic kinetic energies and mass–velocity corrections in diatomic molecules" @default.
• W2075703752 cites W1511650891 @default.
• W2075703752 cites W1624531027 @default.
• W2075703752 cites W1986738851 @default.
• W2075703752 cites W1990764552 @default.
• W2075703752 cites W1995744361 @default.
• W2075703752 cites W2003870665 @default.
• W2075703752 cites W2015111960 @default.
• W2075703752 cites W2017070208 @default.
• W2075703752 cites W2029444423 @default.
• W2075703752 cites W2041615596 @default.
• W2075703752 cites W2048561902 @default.
• W2075703752 cites W2053396623 @default.
• W2075703752 cites W2061558345 @default.
• W2075703752 cites W2062582452 @default.
• W2075703752 cites W2062954282 @default.
• W2075703752 cites W2065413792 @default.
• W2075703752 cites W2067234809 @default.
• W2075703752 cites W2072201909 @default.
• W2075703752 cites W2073500861 @default.
• W2075703752 cites W2073716631 @default.
• W2075703752 cites W2076482505 @default.
• W2075703752 cites W2078057866 @default.
• W2075703752 cites W2081270947 @default.
• W2075703752 cites W2086370012 @default.
• W2075703752 cites W2087209204 @default.
• W2075703752 cites W2087548433 @default.
• W2075703752 cites W2088713558 @default.
• W2075703752 cites W2091826907 @default.
• W2075703752 cites W2093197547 @default.
• W2075703752 cites W2133742679 @default.
• W2075703752 cites W2136388649 @default.
• W2075703752 cites W2159760101 @default.
• W2075703752 cites W2169847112 @default.
• W2075703752 cites W2252424823 @default.
• W2075703752 cites W2607590063 @default.
• W2075703752 cites W2911730856 @default.
• W2075703752 cites W3004673506 @default.
• W2075703752 cites W4246856326 @default.
• W2075703752 cites W4256022466 @default.
• W2075703752 doi "https://doi.org/10.1063/1.451771" @default.
• W2075703752 hasPublicationYear "1986" @default.
• W2075703752 type Work @default.
• W2075703752 sameAs 2075703752 @default.
• W2075703752 citedByCount "11" @default.
• W2075703752 countsByYear W20757037522022 @default.
• W2075703752 countsByYear W20757037522023 @default.
• W2075703752 crossrefType "journal-article" @default.
• W2075703752 hasAuthorship W2075703752A5051630394 @default.
• W2075703752 hasConcept C10138342 @default.
• W2075703752 hasConcept C102931765 @default.
• W2075703752 hasConcept C111806078 @default.
• W2075703752 hasConcept C121332964 @default.
• W2075703752 hasConcept C135889238 @default.
• W2075703752 hasConcept C147789679 @default.
• W2075703752 hasConcept C152991086 @default.
• W2075703752 hasConcept C162324750 @default.
• W2075703752 hasConcept C184779094 @default.
• W2075703752 hasConcept C185592680 @default.
• W2075703752 hasConcept C26582661 @default.
• W2075703752 hasConcept C32909587 @default.
• W2075703752 hasConcept C60718061 @default.
• W2075703752 hasConcept C62396407 @default.
• W2075703752 hasConcept C62520636 @default.
• W2075703752 hasConcept C74650414 @default.
• W2075703752 hasConcept C81263218 @default.
• W2075703752 hasConcept C84551667 @default.
• W2075703752 hasConceptScore W2075703752C10138342 @default.
• W2075703752 hasConceptScore W2075703752C102931765 @default.
• W2075703752 hasConceptScore W2075703752C111806078 @default.
• W2075703752 hasConceptScore W2075703752C121332964 @default.
• W2075703752 hasConceptScore W2075703752C135889238 @default.
• W2075703752 hasConceptScore W2075703752C147789679 @default.
• W2075703752 hasConceptScore W2075703752C152991086 @default.
• W2075703752 hasConceptScore W2075703752C162324750 @default.
• W2075703752 hasConceptScore W2075703752C184779094 @default.
• W2075703752 hasConceptScore W2075703752C185592680 @default.
• W2075703752 hasConceptScore W2075703752C26582661 @default.
• W2075703752 hasConceptScore W2075703752C32909587 @default.
• W2075703752 hasConceptScore W2075703752C60718061 @default.
• W2075703752 hasConceptScore W2075703752C62396407 @default.
• W2075703752 hasConceptScore W2075703752C62520636 @default.
• W2075703752 hasConceptScore W2075703752C74650414 @default.
• W2075703752 hasConceptScore W2075703752C81263218 @default.
• W2075703752 hasConceptScore W2075703752C84551667 @default.
• W2075703752 hasIssue "8" @default.
• W2075703752 hasLocation W20757037521 @default.
• W2075703752 hasOpenAccess W2075703752 @default.
• W2075703752 hasPrimaryLocation W20757037521 @default.
• W2075703752 hasRelatedWork W1966562089 @default.
• W2075703752 hasRelatedWork W1970878789 @default.
• W2075703752 hasRelatedWork W2012768516 @default.
• W2075703752 hasRelatedWork W2014077238 @default.

• next