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• W2075715650 abstract "In this study, the N-methylpolyvinylpyridinuim polymer has for the first time been used as a silica surface modifier for CE in combination with ESI MS (CE-ESI-MS). The compatibility for ESI-MS was demonstrated by the analysis of peptides and protein digests. The N-methylpolyvinylpyridium surface interacts electrostatically with the ionized silanol groups, giving a cationic surface with a reversed EOF. The surface modifier gave rapid and repeatable separations of peptides, proteins and protein digests at acidic pH for more than 4 h of continuous use. The CE separation yielded peak efficiencies of up to 4.3 x 10(5) plates/m. The surface coating is highly compatible with ESI and facilitates the separation and analysis of complex peptide mixtures as shown by the analysis of BSA digests." @default.
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• W2075715650 date "2010-03-26" @default.
• W2075715650 modified "2023-10-16" @default.
• W2075715650 title "Analysis of peptides using <i>N</i>‐methylpolyvinylpyridium as silica surface modifier for CE‐ESI‐MS" @default.
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• W2075715650 doi "https://doi.org/10.1002/elps.200900536" @default.
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