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- W2075748900 abstract "Fischer-Tropsch synthesis mechanisms have been postulated in which alkyl fragments are both the chain-growing intermediate and the precursor to hydrocarbon products. The conversion of COH2 into small alkyl fragments was investigated by scavenging C1C3 alkyl species from the surface of an iron catalyst during Fischer-Tropsch synthesis. The experiments were performed in a steady-state mode revealing that pyridine did not inhibit or poison the Fischer-Tropsch reaction, rather it suppressed the overall rate slightly. Scavenged α-alkylpyridine distributions were dependent upon synthesis variables and displayed a dependence which was proportional to the dependence of C1 C3 Fischer-Tropsch products. These dependences are used to demonstrate that alkyl fragments are the immediate precursors to Fischer-Tropsch products." @default.
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- W2075748900 date "1984-04-01" @default.
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- W2075748900 title "Evidence for alkyl intermediates during Fischer-Tropsch synthesis and their relation to hydrocarbon products" @default.
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- W2075748900 doi "https://doi.org/10.1016/0021-9517(84)90369-5" @default.
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