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- W2075777661 abstract "Treatment of UI3(THF)4 with [M(Et2O)][SPSMe] (M = Li, K; [SPSMe]− = 1-methyl-2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine anion) gave the cationic tris SPS complex [U(SPSMe)3]I (1). Similar reaction of U(BH4)3(THF)3 and [M(Et2O)][SPSMe] afforded, in addition to the [U(SPS)3]+ cation, crystals of the sulfido complex [U{(μ3-S)4U3(SPSMe)3(BH4)3}2] (2). The metal environment in 1 is a tricapped trigonal prism and the core of the heptanuclear cluster 2 is a corner-shared double-cubane." @default.
- W2075777661 created "2016-06-24" @default.
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- W2075777661 date "2009-06-01" @default.
- W2075777661 modified "2023-10-18" @default.
- W2075777661 title "A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element" @default.
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- W2075777661 doi "https://doi.org/10.1016/j.poly.2009.03.027" @default.
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