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- W2075804705 abstract "Trimethyltin compounds Me3Sn-R(R = CH=CH2, CF=CF2, or C≡CPh) are selective reagents for the synthesis of unsaturated hydrocarbyl derivatives such as trans-PtCl(R)(PPhEt2)2, by R/Cl exchange or oxidative addition (e.g., to Pt(PPh3)3); single crystal X-ray analyses of two such compounds (R = CH=CH2 or C≡CPh) show that the trans-influence of R has only a low sensitivity to hybridisation at carbon, with sp3 > sp ⩾ sp2." @default.
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- W2075804705 date "1973-11-01" @default.
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- W2075804705 title "The synthesis, structure, and reactions of some simple unsaturated σ-hydrocarbylplatinum(II) complexes" @default.
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- W2075804705 doi "https://doi.org/10.1016/s0022-328x(00)80640-3" @default.
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