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- W2075806307 abstract "The Schiff base ligands bis(acetylacetone)-m-phenylenediimine (L1) and bis(acetylacetone)-p-phenylenediimine (L2) can be made to coordinate to Cd(II) without deprotonation. The products have the stoichiometries Cd(L1)2(NO3)2 and Cd2(L2)3(NO3)4. Characterization by X-ray crystallography reveals polymeric structures in which Cd is eight-coordinate in the former and seven-coordinate in the latter. The nitrate groups are bidentate. The Schiff base ligands coordinate to Cd only through oxygen atoms and function as bridging bidentate keto-amine tautomers such that the NH⋯O hydrogen bonding networks present in the free ligands are preserved." @default.
- W2075806307 created "2016-06-24" @default.
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- W2075806307 date "2003-11-01" @default.
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- W2075806307 title "Tautomerism in complexes with neutral tetradentate Schiff base ligands: the X-ray structures of cadmium(II) nitrate complexes of bis(acetylacetone)-m-phenylenediimine and bis(acetylacetone)-p-phenylenediimine" @default.
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- W2075806307 doi "https://doi.org/10.1016/s0277-5387(03)00474-1" @default.
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