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- W2075808655 abstract "Ternary crystalline dispersions of 10 wt % sodium stearate (NaSt) in mixtures of water and propylene glycol (PG) have been investigated at the atomic, molecular, and microscopic levels. Two lamellar crystalline structures, α-NaSt and β-NaSt, have been determined by X-ray diffraction. Compared with β-NaSt, α-NaSt exhibits a larger bilayer thickness, a more ordered packing of hydrocarbon chains, and dissolves at a lower temperature in the PG/H2O mixture. A transformation from β-NaSt to α-NaSt is observed upon aging in a PG concentration range of 60−95 wt % in mixtures of H2O and PG. The aging transformation progresses faster and to a greater extent as the PG content increases. Additionally, the fibrous crystallites of α-NaSt are more bundled and oriented compared to those of β-NaSt, as revealed by two-dimensional SAXS (small-angle X-ray scattering) and cryo-SEM (cryogenic scanning electron microscopy). The conformation and mobility of the alkane chains in α-NaSt and β-NaSt have been further studied by solid-state 13C CP MAS (cross-polarization magic-angle spinning) NMR. A greater percentage of trans chain conformation is found in α-NaSt, and the rigidity of the chains is higher. A stronger association of PG with β-NaSt crystals than with α-NaSt crystals is also indicated by the appearance of the PG carbon resonances in the solid-state NMR spectrum." @default.
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- W2075808655 date "2001-08-09" @default.
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- W2075808655 title "Solvent Modulated Polymorphism of Sodium Stearate Crystals Studied by X-ray Diffraction, Solid-State NMR, and Cryo-SEM" @default.
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- W2075808655 doi "https://doi.org/10.1021/jp010532h" @default.
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