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- W2075821922 abstract "Korrosionsschichten auf Stahl nach Exposition in Wasser mit bestimmter Harte und Chloridgehalt wurden hinsichtlich der Wirksamkeit beigefugter organischer Inhibitoren mittels Mosbauer- und ESCA-Spektroskopie untersucht. Es entstehen relativ dicke Schichten mit einem unerwartet niedrigen Eisengehalt in Form von FeOOH. Die Schichten enthalten merkliche Mengen von Ionen aus der Testlosung und auch Abbauprodukte der Inhibitormolekule. Letztere werden anscheinend in dem korrosiven Medium zersetzt. Es ist anzunehmen, das das Gesamtmolekul zwar den Transport des Inhibitors zum Metall beeinflust, die eigentliche Inhibierung aber allein durch funktionelle Gruppen erfolgt.Mossbauer and ESCA investigations on the formation of oxidic iron phases in aqueous solution under the influence of organic corrosion inhibitorsCorrosion layers on steel grown in water of well defined hardness and chloride concentration were studied by Mossbauer and ESCA spectroscopy with particular emphasis on the influence of added organic inhibitors. Relatively thick layers were found with an unexpectedly small iron content (as FeOOH). The layers contain a remarkable amount of constituent ions from the solution and fragments of the inhibitors. The latter seem to be decomposed by the corrosive medium: It is assumed that the whole organic molecule determines the kind of transportation of the inhibitor to the iron metal, but that the inhibition itself is due to functional groups only." @default.
- W2075821922 created "2016-06-24" @default.
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- W2075821922 date "1982-01-01" @default.
- W2075821922 modified "2023-10-03" @default.
- W2075821922 title "Mößbauer- und ESCA-Untersuchungen zur Bildung oxidischer Eisenphasen in wäßrigen Medien unter der Einwirkung organischer Korrosionsinhibitoren" @default.
- W2075821922 cites W2044207055 @default.
- W2075821922 cites W2321685571 @default.
- W2075821922 doi "https://doi.org/10.1002/maco.19820330106" @default.
- W2075821922 hasPublicationYear "1982" @default.
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