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- W2075835518 abstract "A series of cyclopalladated anils of benzoylferrocene with the general formula [Pd{(η5-C5H5)Fe} (η5-C5H3CPhNAr)Cl(PPh3)] (Ar = a variety of substituted phenyls and β = napthyl) were synthesized by transmetallation reaction of the corresponding cyclomercurated derivatives [HgCl{(η5-C5H5}Feη5-C5H3CPhNAr] with lithium tetrachloropalladate or by direct cyclopalladation reaction of the corresponding ferrocenylketimines [(ν5-C5H5)Fe(ν5-C5H4CPh = NAr)], followed by the treatment of the resulting products with triphenylphosphine. The composition and the structure of the metallocycles were characterized by elemental analysis, IR, 1H NMR and two-dimensional NOESY spectra. Some spectral features of these complexes were also discussed." @default.
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- W2075835518 date "1995-12-01" @default.
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- W2075835518 title "Synthesis of cylopalladated anils of benzoylferrocene via transmetallation reaction of mercurated ferrocenylketimines with Li2PdCl4 or by direct cyclopalladation reaction of ferrocenylketimines" @default.
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- W2075835518 doi "https://doi.org/10.1016/0022-328x(95)05597-5" @default.
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