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- W2075896679 abstract "The synthesis of hydrophobic/hydrophilic hybrid polymers based on polydimethylsiloxanes (PDMS) and carbohydrate derivatives involving a hydrosilylation step is reported. Starting with poly(dimethyl-co-hydromethyl)siloxanes (PDMS-co-HMS), O-acetylated N-allylaldonamides of various sugars can be attached to the siloxane backbone using platinum catalysts. The characteristics of different transition metal complexes in the polymer-analogous formation of SiC bonds are investigated. A generalized reaction pathway applicable to several reducing carbohydrates is established to synthesize aldonamide siloxanes in a broad variety of molecular weight and composition. The products obtained, “sweet siloxanes”, are characterized by g.p.c., FTi.r. spectrometry and 13C n.m.r. spectroscopy." @default.
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- W2075896679 date "1998-01-01" @default.
- W2075896679 modified "2023-10-02" @default.
- W2075896679 title "Synthesis of aldonamide siloxanes by hydrosilylation" @default.
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- W2075896679 doi "https://doi.org/10.1016/s0032-3861(97)00443-6" @default.
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