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• W2075980709 abstract "Abstract Layered oxides, ruthenium-substituted Li 2 MnO 3 , were synthesized at 800 °C and 1200 °C. Their phase relation and electrical and electrochemical properties were investigated. Li 2 Mn 1− x Ru x O 3 synthesized at 800 °C clearly separated into two phases, manganese-rich and ruthenium-rich phases, except for the narrow composition range of 0 ≤  x  ≤ 0.05, while Li 2 Mn 1− x Ru x O 3 synthesized at 1200 °C formed two solid solutions in the whole composition range across a structural transition between x  = 0.6 and 0.8. The electrical resistivity of Li 2 Mn 1− x Ru x O 3 decreased with increasing ruthenium content. Li 2 Mn 0.2 Ru 0.8 O 3 ( x  = 0.8) synthesized at 1200 °C showed the lowest resistivity of 5.7 × 10 2  Ω cm at room temperature. The discharge capacity and cycling performance were improved by the ruthenium substitution. Li 2 Mn 0.4 Ru 0.6 O 3 ( x  = 0.6) exhibited a discharge capacity of 192 mAh g −1 in the initial cycle and 169 mAh g −1 in the tenth cycle with high and almost constant charge–discharge efficiencies of 99% from the second to tenth cycle at a current rate of 1/10 C . The ruthenium substitution to Li 2 MnO 3 is quite effective to improve electrical conductivity and charge–discharge performance." @default.
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• W2075980709 date "2011-08-01" @default.
• W2075980709 modified "2023-09-23" @default.
• W2075980709 title "Synthesis, phase relation and electrical and electrochemical properties of ruthenium-substituted Li2MnO3 as a novel cathode material" @default.
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• W2075980709 doi "https://doi.org/10.1016/j.jpowsour.2010.11.150" @default.
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