Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076012854> ?p ?o ?g. }
- W2076012854 abstract "The molecule 3,3(')-diethyl-2,2(')-thiacyanine isomerizes after irradiation with light of the proper wavelength. After excitation, it undergoes a transition, in which one or more conical intersections are involved, back to the ground state to form different product photoisomers. The dynamics before and directly after the transition back to the ground state is investigated by transient absorption spectroscopy in a wavelength region of 360-950 nm, as well as by fluorescence upconversion. It is shown that the excited-state dynamics are governed by two time scales: a short one with a decay time of less than 2 ps and a long one with about 9 ps. A thorough comparison of the experimental results with those of configuration interaction singles and time-dependent density functional theory calculations suggests that these dynamics are related to two competing pathways differing in the molecular twisting on the excited surface after photoexcitation. From the experimental point of view this picture arises taking into account the time scales for ground-state bleach, excited-state absorption, stimulated emission, fluorescence, and assumed hot ground-state absorption both in the solvent methanol and ethylene glycol." @default.
- W2076012854 created "2016-06-24" @default.
- W2076012854 creator A5008062001 @default.
- W2076012854 creator A5026769752 @default.
- W2076012854 creator A5032351093 @default.
- W2076012854 creator A5035700677 @default.
- W2076012854 creator A5085925824 @default.
- W2076012854 date "2006-07-27" @default.
- W2076012854 modified "2023-09-25" @default.
- W2076012854 title "Femtosecond study on the isomerization dynamics of NK88. II. Excited-state dynamics" @default.
- W2076012854 cites W1963683620 @default.
- W2076012854 cites W1973346993 @default.
- W2076012854 cites W1981872991 @default.
- W2076012854 cites W1982591311 @default.
- W2076012854 cites W1984997890 @default.
- W2076012854 cites W1986491522 @default.
- W2076012854 cites W1987047380 @default.
- W2076012854 cites W1988103931 @default.
- W2076012854 cites W1988973604 @default.
- W2076012854 cites W1989021984 @default.
- W2076012854 cites W1989208756 @default.
- W2076012854 cites W1989968418 @default.
- W2076012854 cites W1994538342 @default.
- W2076012854 cites W1996491487 @default.
- W2076012854 cites W1996531112 @default.
- W2076012854 cites W1996597449 @default.
- W2076012854 cites W2000500972 @default.
- W2076012854 cites W2001177502 @default.
- W2076012854 cites W2008048271 @default.
- W2076012854 cites W2008164563 @default.
- W2076012854 cites W2008423326 @default.
- W2076012854 cites W2016800344 @default.
- W2076012854 cites W2022588273 @default.
- W2076012854 cites W2023488932 @default.
- W2076012854 cites W2025771439 @default.
- W2076012854 cites W2027331236 @default.
- W2076012854 cites W2028022118 @default.
- W2076012854 cites W2031688629 @default.
- W2076012854 cites W2033557627 @default.
- W2076012854 cites W2043367490 @default.
- W2076012854 cites W2046164904 @default.
- W2076012854 cites W2053036150 @default.
- W2076012854 cites W2053201390 @default.
- W2076012854 cites W2054182760 @default.
- W2076012854 cites W2056967289 @default.
- W2076012854 cites W2058947069 @default.
- W2076012854 cites W2059824119 @default.
- W2076012854 cites W2068228867 @default.
- W2076012854 cites W2069674497 @default.
- W2076012854 cites W2072321138 @default.
- W2076012854 cites W2074947833 @default.
- W2076012854 cites W2075419850 @default.
- W2076012854 cites W2077506595 @default.
- W2076012854 cites W2078746605 @default.
- W2076012854 cites W2082518431 @default.
- W2076012854 cites W2095179907 @default.
- W2076012854 cites W2111383755 @default.
- W2076012854 cites W2113358363 @default.
- W2076012854 cites W2120664424 @default.
- W2076012854 cites W2140083203 @default.
- W2076012854 cites W2147303166 @default.
- W2076012854 cites W2151954645 @default.
- W2076012854 cites W2170542823 @default.
- W2076012854 doi "https://doi.org/10.1063/1.2210939" @default.
- W2076012854 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16942162" @default.
- W2076012854 hasPublicationYear "2006" @default.
- W2076012854 type Work @default.
- W2076012854 sameAs 2076012854 @default.
- W2076012854 citedByCount "28" @default.
- W2076012854 countsByYear W20760128542012 @default.
- W2076012854 countsByYear W20760128542013 @default.
- W2076012854 countsByYear W20760128542014 @default.
- W2076012854 countsByYear W20760128542015 @default.
- W2076012854 countsByYear W20760128542016 @default.
- W2076012854 countsByYear W20760128542017 @default.
- W2076012854 countsByYear W20760128542018 @default.
- W2076012854 crossrefType "journal-article" @default.
- W2076012854 hasAuthorship W2076012854A5008062001 @default.
- W2076012854 hasAuthorship W2076012854A5026769752 @default.
- W2076012854 hasAuthorship W2076012854A5032351093 @default.
- W2076012854 hasAuthorship W2076012854A5035700677 @default.
- W2076012854 hasAuthorship W2076012854A5085925824 @default.
- W2076012854 hasConcept C11630735 @default.
- W2076012854 hasConcept C120665830 @default.
- W2076012854 hasConcept C121332964 @default.
- W2076012854 hasConcept C121745418 @default.
- W2076012854 hasConcept C125287762 @default.
- W2076012854 hasConcept C126661725 @default.
- W2076012854 hasConcept C133279788 @default.
- W2076012854 hasConcept C145148216 @default.
- W2076012854 hasConcept C155220765 @default.
- W2076012854 hasConcept C161790260 @default.
- W2076012854 hasConcept C167735695 @default.
- W2076012854 hasConcept C178790620 @default.
- W2076012854 hasConcept C181500209 @default.
- W2076012854 hasConcept C184779094 @default.
- W2076012854 hasConcept C185592680 @default.
- W2076012854 hasConcept C20853536 @default.
- W2076012854 hasConcept C24857813 @default.
- W2076012854 hasConcept C32891209 @default.