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- W2076013207 abstract "The structures of the versatile starting compounds for organoiron complexes, the cationic aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 (1b) and the halide complexes (η5-C5Me5)Fe(CO)2-I (2a), (η5-C5Me4Et)Fe(CO)2-I (2b) and (η5-C5Me4Et)Fe(CO)2-Cl (3b), are characterized by X-ray crystallography. Complex 1b [FeO: 2.022(8) Å and 2.043(9) Å, two independent molecules] is the first structurally characterized example of organoiron aqua complexes. Details of the synthetic procedures for the above complexes and the labile cationic THF complexes [η5-C5R5)Fe(CO)2(THF)]BF4 (4) are disclosed, and the dissociation equilibrium of 4 is confirmed by means of variable temperature 1H-NMR as well as saturation transfer experiment." @default.
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- W2076013207 title "Some additional aspects of versatile starting compounds for cationic organoiron complexes: molecular structure of the aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 and solution behavior of the THF complex [(η5C5R5)Fe(CO)2(THF)]BF4" @default.
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- W2076013207 doi "https://doi.org/10.1016/0022-328x(95)05918-f" @default.
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