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- W2076016065 abstract "The regioselectivity in the oxidation of different types of 3-keto steroids with potassium superoxide in the presence of 18-crown-6 has been investigated. In all cases, the reaction products are directly related to the enolization process of the substrates. The oxidation of a 2-enolate results in oxidative cleavage of ring A with loss of carbon monoxide to give the lactols (2) and (10) and the aldehyde (8). However, the oxidation of 4-enolates occurs with oxidative cleavage of ring A to give the ketones (7) and (12), the latter with loss of carbon monoxide." @default.
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- W2076016065 date "1986-01-01" @default.
- W2076016065 modified "2023-10-09" @default.
- W2076016065 title "Regioselectivity of the reaction of 3-keto steroids with potassium superoxide" @default.
- W2076016065 doi "https://doi.org/10.1039/p19860001523" @default.
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