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- W2076031293 abstract "A gas-phase u.v. photoelectron spectroscopic study is reported on some para-substituted styryl methylsulphones in which the para-substituent varies in electronegativity and conjugating ability. The main purpose was to observe the substituent effect on electronic structure. The spectral analysis and the trends in ionization energies relative to the highest MOs show that the substituent has both short- and long- range effects, influencing even the orbitals of the –SO2Me group. Satisfactory linear relationships were found between the spectral data for the three highest MOs and the Hammett σp values, the wavenumbers of the SO2 stretching vibrations, and the 13C n.m.r. shifts for C-1 of the styryl group." @default.
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- W2076031293 date "1984-01-01" @default.
- W2076031293 modified "2023-09-27" @default.
- W2076031293 title "Substituent effects on the electronic structure of some styryl methyl sulphones studied by ultraviolet photoelectron spectroscopy" @default.
- W2076031293 doi "https://doi.org/10.1039/p29840000533" @default.
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