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- W2076062533 abstract "Abstract The inclusion into β-cyclodextrin (β-Cyd) by the two methoxypsoralen isomers (5-methoxypsoralen (5-MOP) and 8-methoxypsoralen (8-MOP)) has been extensively studied by reverse phase liquid chromatography (RP-HPLC). Some important quantitative data concerning the complexation in a dynamic flow system have been drawn. The stoichiometry of the complex formation (1:1 in all instances), and the affinity constants with the β-Cyd cavity (Kf) of the two guest compounds, have been established. By taking into account the competitive effect of the organic modifier of the eluent (methanol), the Kfs of both compounds have been extrapolated to pure water (233 M−1 and 106 M−1 for 5-MOP and 8-MOP, respectively). On the other hand, the established stoichiometry and affinity constants have been interpreted in terms of enthalpy and entropy changes. Finally, the importance of the position of the methoxy substituent has been underlined and seems to rule the quality of the fit of each isomer within the inner cavity of β-cyclodextrin." @default.
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- W2076062533 date "1993-12-01" @default.
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- W2076062533 title "Liquid chromatographic study of two methoxypsoralen isomers with β-cyclodextrin" @default.
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- W2076062533 doi "https://doi.org/10.1080/10610279308029840" @default.
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