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- W2076064141 abstract "The UPS and XPS spectra of Xe adsorbed on clean, O, CO, and Xe covered W(110) surfaces and the UPS spectrum for Kr on clean and O covered W(110) surfaces have been investigated. On clean W, Xe and Kr show a splitting of the 5p32 and 4p32 hole states respectively. For Xe the coverage dependence of this splitting was investigated in detail; neither the positions nor the intensity ratio of the substates are coverage dependent for θ ⩾ 0.04, suggesting that splitting is due to differences in the image interaction of the mj = ±32 and mj = ±12 components. For Xe equal shifts, relative to vacuum, of ~1.0 eV were observed for 5p, 4d, and 3d levels, suggesting that initial state effects are small. Image interaction for Xe and Kr on clean W could best be fitted by assuming an increase, rather than a decrease in the effective hole-image separation from the nominal value, suggesting that the image plane is moved back into the metal by a screening length. For Xe adsorbed on XeW(110), or on virgin-COW(110) polarization of the intermediate layers was found to contribute significantly to relaxation. Coadsorbed oxygen broadened Xe 5p and Kr 4p peaks. There was an almost linear relation between O 2p UPS intensity at the energies of the various peaks and the amounts of broadening, suggesting that the latter results from resonance neutralization by electrons from the O 2p states." @default.
- W2076064141 created "2016-06-24" @default.
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- W2076064141 date "1983-05-01" @default.
- W2076064141 modified "2023-09-25" @default.
- W2076064141 title "Photoemission of Xe and Kr adsorbed on the W(110) plane" @default.
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- W2076064141 doi "https://doi.org/10.1016/0039-6028(83)90048-1" @default.
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