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- W2076095346 abstract "Resume Study of the stretching bands ν NH and ν ND for twenty C-alkylated and C-arylated secondary aziridines and their deuteriated homologs, allowed us to distinguish invertomers of different energies which can exist when aziridines are dissymetrically substituted on the carbon atoms. The major invertomer is that with hydrogen atom (N)H or deuterium atom (N)D situated in the ring side the least sterically hindered. The influence of carbon atom substituents on the frequencies ν NH or ν ND appeared essentially like a “through space” effect and not like a bond transmitting effect. When one side is more hindered than the other, the most thermodynamically stable invertomer ((N)H in the side the least hindered) exists alone." @default.
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- W2076095346 date "1974-03-01" @default.
- W2076095346 modified "2023-10-02" @default.
- W2076095346 title "Aziridines—VII. Mise en évidence par spectrographie infrarouge d'invertomères résultant de l'inversion de l'azote dans les aziridines secondaires" @default.
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- W2076095346 doi "https://doi.org/10.1016/0584-8539(74)80193-5" @default.
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