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- W2076100498 abstract "Positive molecular ion formation in plasma desorption (PD) by hydride abstraction leading to [M − H]+ molecular ions is not a frequently observed phenomenon. An example of a compound that exhibits an [M − H]+ molecular ion in its PD spectrum is the neutral lipid cholesterol. Data on the initial radial velocity distribution of the [M − H]+ ion of cholesterol are presented and compared to data on the radial velocity distribution of the M+ molecular ion of a structurally similar compound (ergosterol). The distribution for [M − H]+ cholesterol ions is broader and its centroid is closer to zero radial velocity than the corresponding distribution for ergosterol M+ ions. These data support a model suggesting formation of [M − H]+ by a “self” chemical ionization type reaction." @default.
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- W2076100498 date "1993-01-01" @default.
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- W2076100498 title "On molecular ion formation by hydride abstraction in plasma desorption mass spectrometry" @default.
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