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• W2076102227 endingPage "118" @default.
• W2076102227 startingPage "109" @default.
• W2076102227 abstract "Polymeric ligands, such as 2-substituted pentanedioic acid (2), 2-substituted propanoic acid (3), and deoxylactit-1-yl (4) derivatives of chitosan (1), were used to prepare copper complexes that are widely soluble in aqueous solution. EPR results (100 K) show that all association complexes basically have a tetragonal symmetry. Visible CD spectra suggest, however, that the order of increasing departure from this geometry is Cu-(1) approximately Cu-(3) less than Cu-(2) less than or equal to Cu-(4), the lack of sterically constraining side-chains in (1) and (3) allowing a more symmetric arrangement of ligands around the central metal ion. Results on the catalytic activity of the association complexes for air oxidation of catechol derivatives are also presented." @default.
• W2076102227 created "2016-06-24" @default.
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• W2076102227 date "1992-05-01" @default.
• W2076102227 modified "2023-10-16" @default.
• W2076102227 title "Copper complexes immobilized to chitosan" @default.
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• W2076102227 doi "https://doi.org/10.1016/0162-0134(92)80014-m" @default.
• W2076102227 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/1326023" @default.
• W2076102227 hasPublicationYear "1992" @default.
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