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- W2076111173 abstract "Hydrocyanation of 3-methylpentane-2,4-dione stereospecifically gave trans,trans-iminolactone 1, whose configuration was established by X-ray diffraction of the corresponding lactone 2; the rate of cyclization of the diastereoisomeric lactonic acids 3a,b and their esters 4a,b into dilactone 5 was controlled sterically by the methyl groups with cis,cis -isomers 3b , 4b predominating ; alcoholysis of 5 regiospecifically afforded ester 4b ." @default.
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- W2076111173 date "1997-01-01" @default.
- W2076111173 modified "2023-09-27" @default.
- W2076111173 title "Stereocontrolled synthesis and cyclization of (+,−)-α,α’-dihydroxy-α,α ’, β-trimethylglutaric acid derivatives" @default.
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- W2076111173 doi "https://doi.org/10.1070/mc1997v007n02abeh000706" @default.
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