FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076121330> ?p ?o ?g. }

• W2076121330 endingPage "6872" @default.
• W2076121330 startingPage "6866" @default.
• W2076121330 abstract "A new flexible porous coordination polymer (PCP), {[Gd(2)(L)(3)(dmf)(4)]·4DMF·3H(2)O}(n) (1), was synthesized under solvothermal condition by reacting [Gd(NO(3))(3)]·6H(2)O with the ligand 2,6,2',6'-tetranitro-biphenyl-4,4'-dicarboxylic acid (H(2)L). Compound 1 had a 3D coordination polymeric structure with two types of 1D channels (A and B) that were occupied by DMF and water molecules. When crystals of 1 were separately exposed to vapors of various aromatic aldehydes, either the lattice or both the lattice and metal-bound solvent molecules were replaced by aldehyde molecules. The aldehyde molecules inside the pores spontaneously underwent cyanosilylation and Knoevenagel condensation reactions upon exposure to vapors of trimethylsilyl cyanide and malononitrile, respectively. These reactions took place at ambient temperature and pressure. Moreover, both the reactants and the products translocated from one cavity to another. The products that occupied the cavity were expunged upon exposure to the vapors of an aldehyde. Because crystallinity was maintained during these chemical transformations, direct crystallographic observation was possible. Herein, we showed that confinement of the reactants inside the void spaces of the PCP led to the products; we also assessed catalytic activities of this PCP in bulk quantities." @default.
• W2076121330 created "2016-06-24" @default.
• W2076121330 creator A5011037240 @default.
• W2076121330 creator A5019478816 @default.
• W2076121330 creator A5040678170 @default.
• W2076121330 creator A5048155732 @default.
• W2076121330 creator A5050043760 @default.
• W2076121330 date "2012-04-20" @default.
• W2076121330 modified "2023-10-02" @default.
• W2076121330 title "Direct Crystallographic Observation of Catalytic Reactions inside the Pores of a Flexible Coordination Polymer" @default.
• W2076121330 cites W123206705 @default.
• W2076121330 cites W1628423641 @default.
• W2076121330 cites W1963587266 @default.
• W2076121330 cites W1965010276 @default.
• W2076121330 cites W1967109824 @default.
• W2076121330 cites W1970188546 @default.
• W2076121330 cites W1974697299 @default.
• W2076121330 cites W1979243460 @default.
• W2076121330 cites W1979264110 @default.
• W2076121330 cites W1982179393 @default.
• W2076121330 cites W1983899252 @default.
• W2076121330 cites W1987652875 @default.
• W2076121330 cites W1989118706 @default.
• W2076121330 cites W1991332798 @default.
• W2076121330 cites W1991704107 @default.
• W2076121330 cites W2009368971 @default.
• W2076121330 cites W2010637586 @default.
• W2076121330 cites W2021767761 @default.
• W2076121330 cites W2027685691 @default.
• W2076121330 cites W2039691813 @default.
• W2076121330 cites W2050644059 @default.
• W2076121330 cites W2052865601 @default.
• W2076121330 cites W2053700726 @default.
• W2076121330 cites W2060912357 @default.
• W2076121330 cites W2066436885 @default.
• W2076121330 cites W2066991705 @default.
• W2076121330 cites W2090748133 @default.
• W2076121330 cites W2096635410 @default.
• W2076121330 cites W2100300640 @default.
• W2076121330 cites W2102573766 @default.
• W2076121330 cites W2109981002 @default.
• W2076121330 cites W2111143420 @default.
• W2076121330 cites W2120680970 @default.
• W2076121330 cites W2122508191 @default.
• W2076121330 cites W2126595837 @default.
• W2076121330 cites W2129501054 @default.
• W2076121330 cites W2133084791 @default.
• W2076121330 cites W2133316123 @default.
• W2076121330 cites W2152932169 @default.
• W2076121330 cites W2158817381 @default.
• W2076121330 cites W2159778994 @default.
• W2076121330 cites W2164182744 @default.
• W2076121330 cites W2167145400 @default.
• W2076121330 cites W2169834323 @default.
• W2076121330 cites W2171499252 @default.
• W2076121330 cites W2319249801 @default.
• W2076121330 cites W2328804766 @default.
• W2076121330 cites W2951832749 @default.
• W2076121330 cites W4211144729 @default.
• W2076121330 cites W4233612632 @default.
• W2076121330 cites W4251132537 @default.
• W2076121330 cites W4252019908 @default.
• W2076121330 doi "https://doi.org/10.1002/chem.201200046" @default.
• W2076121330 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22522890" @default.
• W2076121330 hasPublicationYear "2012" @default.
• W2076121330 type Work @default.
• W2076121330 sameAs 2076121330 @default.
• W2076121330 citedByCount "105" @default.
• W2076121330 countsByYear W20761213302012 @default.
• W2076121330 countsByYear W20761213302013 @default.
• W2076121330 countsByYear W20761213302014 @default.
• W2076121330 countsByYear W20761213302015 @default.
• W2076121330 countsByYear W20761213302016 @default.
• W2076121330 countsByYear W20761213302017 @default.
• W2076121330 countsByYear W20761213302018 @default.
• W2076121330 countsByYear W20761213302019 @default.
• W2076121330 countsByYear W20761213302020 @default.
• W2076121330 countsByYear W20761213302021 @default.
• W2076121330 countsByYear W20761213302022 @default.
• W2076121330 crossrefType "journal-article" @default.
• W2076121330 hasAuthorship W2076121330A5011037240 @default.
• W2076121330 hasAuthorship W2076121330A5019478816 @default.
• W2076121330 hasAuthorship W2076121330A5040678170 @default.
• W2076121330 hasAuthorship W2076121330A5048155732 @default.
• W2076121330 hasAuthorship W2076121330A5050043760 @default.
• W2076121330 hasConcept C115624301 @default.
• W2076121330 hasConcept C161790260 @default.
• W2076121330 hasConcept C178790620 @default.
• W2076121330 hasConcept C185592680 @default.
• W2076121330 hasConcept C188027245 @default.
• W2076121330 hasConcept C192562407 @default.
• W2076121330 hasConcept C2777775765 @default.
• W2076121330 hasConcept C2779825165 @default.
• W2076121330 hasConcept C2780471494 @default.
• W2076121330 hasConcept C2780513484 @default.
• W2076121330 hasConcept C2781432337 @default.
• W2076121330 hasConcept C32909587 @default.
• W2076121330 hasConcept C46275449 @default.

• next