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- W2076121640 abstract "Heterogeneous reactions involving sea‐salt aerosol in the marine troposphere are the major global source for volatile inorganic chlorine. We measured reactant and product species hypothesized to be associated with these chemical transformations as a function of phase, particle size, and altitude over the North Atlantic Ocean during the summer of 1988. Concentrations of HCl were typically less than 1.0 ppbv near the sea surface and decreased with altitude and with distance from the U.S. east coast. Concentrations of Cl volatilized from aerosols were generally equivalent to the corresponding concentrations of HCl and ranged from less than detection limits to 125 nmol m −3 STP. Highest absolute and percentage losses of particulate Cl were typically associated with elevated concentrations of anthropogenic combustion products. Concentrations of product nss SO 4 2− and N0 3 − in coarse aerosol fractions indicate that on average only 38% of measured Cl − deficits could be accounted for by the combined effects of acid‐base desorption and reactions involving nonacidic N gases. We hypothesize a mechanism for the Cl loss initiated by reaction of O 3 at sea‐salt aerosol surfaces, generating Cl 2 followed by rapid photochemical conversion of Cl 2 to HCl via Cl atoms (Cl˙) and eventual recapture of HCl by the aerosol. Simulations with a zero‐dimension (0‐D) photochemical model suggest that oxidation by Cl˙ may be an important tropospheric sink for dimethyl sulfide and hydrocarbons. Under low‐NO x conditions, the rapid cycling of reactive Cl would provide a catalytic loss mechanism for O 3 , which would possibly explain the low O 3 concentrations often observed above the world's oceans." @default.
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- W2076121640 date "1990-12-01" @default.
- W2076121640 modified "2023-09-26" @default.
- W2076121640 title "The geochemical cycling of reactive chlorine through the marine troposphere" @default.
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- W2076121640 cites W1968588400 @default.
- W2076121640 cites W1970652095 @default.
- W2076121640 cites W1973268422 @default.
- W2076121640 cites W1974312262 @default.
- W2076121640 cites W1975581134 @default.
- W2076121640 cites W1978297705 @default.
- W2076121640 cites W1981343038 @default.
- W2076121640 cites W1983486778 @default.
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- W2076121640 cites W1986177075 @default.
- W2076121640 cites W1988485184 @default.
- W2076121640 cites W1993174399 @default.
- W2076121640 cites W1993672312 @default.
- W2076121640 cites W2001703782 @default.
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- W2076121640 cites W2011211035 @default.
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- W2076121640 cites W2020538707 @default.
- W2076121640 cites W2023169887 @default.
- W2076121640 cites W2029531991 @default.
- W2076121640 cites W2029899526 @default.
- W2076121640 cites W2031325607 @default.
- W2076121640 cites W2038749205 @default.
- W2076121640 cites W2044913251 @default.
- W2076121640 cites W2046864327 @default.
- W2076121640 cites W2048241337 @default.
- W2076121640 cites W2053166352 @default.
- W2076121640 cites W2054606365 @default.
- W2076121640 cites W2058427386 @default.
- W2076121640 cites W2059006576 @default.
- W2076121640 cites W2061515112 @default.
- W2076121640 cites W2071687154 @default.
- W2076121640 cites W2074427135 @default.
- W2076121640 cites W2076058279 @default.
- W2076121640 cites W2079657521 @default.
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- W2076121640 cites W2091445981 @default.
- W2076121640 cites W2092877512 @default.
- W2076121640 cites W2095059645 @default.
- W2076121640 cites W2120127151 @default.
- W2076121640 cites W2127240277 @default.
- W2076121640 cites W2128617542 @default.
- W2076121640 cites W2143166840 @default.
- W2076121640 cites W2155704085 @default.
- W2076121640 cites W2163719266 @default.
- W2076121640 cites W314323317 @default.
- W2076121640 cites W4231757523 @default.
- W2076121640 cites W4234716580 @default.
- W2076121640 cites W4235651023 @default.
- W2076121640 cites W4239179679 @default.
- W2076121640 cites W4239632805 @default.
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- W2076121640 cites W4250793775 @default.
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- W2076121640 doi "https://doi.org/10.1029/gb004i004p00407" @default.
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