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- W2076122008 abstract "Perfluorocyclohexa-1,3-diene reacts with alkynes (I) by 1,4-addition to give, exclusively and in good yield,2,3-disubstituted-1,4,5,6,7,7,8,8-octafluorobicyclo[2,2,2]octa-2,5-dienes (II)(X = Y = CF3, Me, Ch2Cl, CO2Et; X = H, Y = CF3, Me, Ch2Cl, Ph; X = CF3, Y = Me) which eliminate tetrafluoroethylene on pyrolysis to give ortho-disubstituted tetrafluorobenzenes, or their further pyrolysis products (III)(X = Y = CF3, Me, H; X = H, Y = CF3, Me, CH2Cl, CO2H, –CCH, CHCH·C6HF4, Ph; X = CF3, Y = Me)." @default.
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- W2076122008 date "1969-01-01" @default.
- W2076122008 modified "2023-09-23" @default.
- W2076122008 title "Diels–Alder reactions of polyfluorocyclohexa-1,3-dienes. Part I. Addition of alkynes to perfluorocyclohexa-1,3-diene. A route to ortho-disubstituted tetrafluorobenzenes" @default.
- W2076122008 doi "https://doi.org/10.1039/j39690000211" @default.
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