Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076124326> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2076124326 endingPage "3020" @default.
- W2076124326 startingPage "3020" @default.
- W2076124326 abstract "Both anomers of the methyl glycoside of 6-O-benzyl-N-dimethylmaleoyl-D-allosamine (6 and 7) are glycosylated exclusively on O3 when reacting with the trichloroacetimidate of peracetylated α-D-galactopyranose (5). This regioselectivity is expected for 6, the α-anomer, as a strong hydrogen bond of its H(O)3 with the carbonyl group of the dimethylmaleoyl group occurs, as shown by NMR temperature dependence. However, this hydrogen bond was not encountered experimentally for 7, the β-anomer. A DFT study of the energies implied in an analog of the glycosylation reaction charged intermediate has explained neatly this behavior, in terms of strong hydrogen bonds occurring at these charged intermediates. This approach explains both the experimental regioselectivities found for 6 and 7, but furthermore the calculations have shown a marked agreement with the regioselectivities found for other related compounds in the literature." @default.
- W2076124326 created "2016-06-24" @default.
- W2076124326 creator A5003370171 @default.
- W2076124326 creator A5013176506 @default.
- W2076124326 creator A5048681901 @default.
- W2076124326 date "2011-01-01" @default.
- W2076124326 modified "2023-10-14" @default.
- W2076124326 title "Regioselectivity of the glycosylation of N-dimethylmaleoyl-protected hexosamine acceptors. An experimental and DFT approach" @default.
- W2076124326 cites W1963630275 @default.
- W2076124326 cites W1968284251 @default.
- W2076124326 cites W1968934713 @default.
- W2076124326 cites W2014169166 @default.
- W2076124326 cites W2017201218 @default.
- W2076124326 cites W2026805158 @default.
- W2076124326 cites W2031854416 @default.
- W2076124326 cites W2046971493 @default.
- W2076124326 cites W2056607207 @default.
- W2076124326 cites W2073924595 @default.
- W2076124326 cites W2078086734 @default.
- W2076124326 cites W2078194698 @default.
- W2076124326 cites W2088640902 @default.
- W2076124326 cites W2095204901 @default.
- W2076124326 cites W2137366329 @default.
- W2076124326 cites W2144101706 @default.
- W2076124326 cites W2147007355 @default.
- W2076124326 cites W2155715825 @default.
- W2076124326 cites W2156908374 @default.
- W2076124326 cites W2951738045 @default.
- W2076124326 cites W4235642743 @default.
- W2076124326 doi "https://doi.org/10.1039/c1ob00021g" @default.
- W2076124326 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21380458" @default.
- W2076124326 hasPublicationYear "2011" @default.
- W2076124326 type Work @default.
- W2076124326 sameAs 2076124326 @default.
- W2076124326 citedByCount "12" @default.
- W2076124326 countsByYear W20761243262012 @default.
- W2076124326 countsByYear W20761243262013 @default.
- W2076124326 countsByYear W20761243262014 @default.
- W2076124326 countsByYear W20761243262015 @default.
- W2076124326 countsByYear W20761243262016 @default.
- W2076124326 countsByYear W20761243262019 @default.
- W2076124326 countsByYear W20761243262020 @default.
- W2076124326 countsByYear W20761243262022 @default.
- W2076124326 crossrefType "journal-article" @default.
- W2076124326 hasAuthorship W2076124326A5003370171 @default.
- W2076124326 hasAuthorship W2076124326A5013176506 @default.
- W2076124326 hasAuthorship W2076124326A5048681901 @default.
- W2076124326 hasConcept C112887158 @default.
- W2076124326 hasConcept C147597530 @default.
- W2076124326 hasConcept C161790260 @default.
- W2076124326 hasConcept C178790620 @default.
- W2076124326 hasConcept C185592680 @default.
- W2076124326 hasConcept C2777313579 @default.
- W2076124326 hasConcept C32909587 @default.
- W2076124326 hasConcept C512968161 @default.
- W2076124326 hasConcept C55493867 @default.
- W2076124326 hasConcept C59759590 @default.
- W2076124326 hasConcept C71240020 @default.
- W2076124326 hasConcept C7947691 @default.
- W2076124326 hasConceptScore W2076124326C112887158 @default.
- W2076124326 hasConceptScore W2076124326C147597530 @default.
- W2076124326 hasConceptScore W2076124326C161790260 @default.
- W2076124326 hasConceptScore W2076124326C178790620 @default.
- W2076124326 hasConceptScore W2076124326C185592680 @default.
- W2076124326 hasConceptScore W2076124326C2777313579 @default.
- W2076124326 hasConceptScore W2076124326C32909587 @default.
- W2076124326 hasConceptScore W2076124326C512968161 @default.
- W2076124326 hasConceptScore W2076124326C55493867 @default.
- W2076124326 hasConceptScore W2076124326C59759590 @default.
- W2076124326 hasConceptScore W2076124326C71240020 @default.
- W2076124326 hasConceptScore W2076124326C7947691 @default.
- W2076124326 hasIssue "8" @default.
- W2076124326 hasLocation W20761243261 @default.
- W2076124326 hasLocation W20761243262 @default.
- W2076124326 hasOpenAccess W2076124326 @default.
- W2076124326 hasPrimaryLocation W20761243261 @default.
- W2076124326 hasRelatedWork W1974756049 @default.
- W2076124326 hasRelatedWork W1976827849 @default.
- W2076124326 hasRelatedWork W1977450780 @default.
- W2076124326 hasRelatedWork W1981122053 @default.
- W2076124326 hasRelatedWork W2057640882 @default.
- W2076124326 hasRelatedWork W2149953781 @default.
- W2076124326 hasRelatedWork W2788704268 @default.
- W2076124326 hasRelatedWork W2952114966 @default.
- W2076124326 hasRelatedWork W2952437957 @default.
- W2076124326 hasRelatedWork W3097905605 @default.
- W2076124326 hasVolume "9" @default.
- W2076124326 isParatext "false" @default.
- W2076124326 isRetracted "false" @default.
- W2076124326 magId "2076124326" @default.
- W2076124326 workType "article" @default.