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- W2076127712 abstract "Abstract The structures of the main tautomers of the Schiff base of salicylaldehyde with ethylamine and its protonated species have been studied by ESI MS, FT-IR as well as 1H, 13C and 15N NMR methods. The spectroscopic methods have provided clear evidence that the Schiff base exists in acetonitrile solution in a low barrier O⋯H⋯N imine–oxo tautomeric form. This form is also energetically favourable as indicated by PM5 calculations. This untypical Schiff base form is stabilized by a resonance effect with the nitro group and the interaction of the intramolecular hydrogen-bonded proton with acetonitrile via a intermolecular hydrogen bond. The protonated Schiff base exists in solution as imine–hydroxy form stabilized by intermolecular hydrogen bonds with nitro groups and solvent molecules." @default.
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- W2076127712 date "2010-04-01" @default.
- W2076127712 modified "2023-09-23" @default.
- W2076127712 title "Spectroscopic and theoretical studies of the protonation of N-(5-nitrosalicylidene)-ethylamine" @default.
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- W2076127712 doi "https://doi.org/10.1016/j.molstruc.2010.01.002" @default.
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