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- W2076132665 abstract "When dilute solid solutions of CF3NNCF3 in argon at 14 K are irradiated by the full light of a medium-pressure mercury arc, no net photolysis occurs, suggesting that the primary photodecomposition products, CF3N2 + CF3, undergo cage recombination. On 122 nm photolysis, cage recombination leads instead to the appearance of prominent infrared absorption of C2F6, suggesting an initial photodecomposition process to form 2 CF3 + N2. Prominent infrared absorptions of CF4 and CF2 were shown to result from the photodecomposition of C2F6. Argon-resonance radiation does not penetrate solid Ar:CF3NNCF3 deposits, but when photolysis is conducted concurrently with deposition a high yield of CF3 is isolated in the argon matrix. Circumvention of the cage effect in this system is attributed to the large amount of excess energy with which the photofragments are formed and to a very short lifetime for the excited electronic state of CF3NNCF3 before dissociation. Even higher yields of CF3 are formed when the Ar:CF3NNCF3 sample is codeposited with a beam of argon atoms excited in a microwave discharge. The effects of concentration and experimental configuration on the product yield are discussed. When the sample is codeposited with a beam of excited neon atoms (16.6–16.8 eV); the most prominent product absorption is that of CF3+, with relatively weak absorptions of CF3, suggesting that at this energy the primary photodecomposition process leads to the formation of CF3 + CF3+ + N2 + e." @default.
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- W2076132665 date "1984-01-01" @default.
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- W2076132665 title "Matrix-isolation study of the decomposition of CF3NNCF3 by photons and by excited rare-gas atom bombardment at energies between 4.9 and 16.8 eV" @default.
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- W2076132665 doi "https://doi.org/10.1016/0301-0104(84)85231-3" @default.
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