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- W2076135636 abstract "2,4-Dimethylhexene-l has been decomposed in single-pulse shock tube experiments. Rate expressions for the initial reactions are and sec−1 at 1.5–5 atm and 1050°K. This leads to ΔH°f300 (CH2 = C(CH3)CH2) = 124 kJ/mol, or an allylic resonance energy of 50 kJ/mol. Rate expressions for the decomposition of the appropriate olefins which yield isobutenyl radicals and methyl, ethyl, isopropyl, n-propyl, t-butyl, and t-amyl radicals, respectively, are presented. The rate expression for the decomposition of isobutenyl radical is (at the beginning of the fall-off region). For the combination of isobutenyl and methyl radicals, the rate constant at 1020°K is Combination of this number and the calculated rate expression for 2-methylbutene-1 decomposition gives S. (1100) = 470 J/mol °K. This yields It is demonstrated that an upper limit for the rate of hydrogen abstraction by isobutenyl from toluene is" @default.
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- W2076135636 date "1973-11-01" @default.
- W2076135636 modified "2023-09-24" @default.
- W2076135636 title "Pyrolysis of 2,4-dimethylhexene-l and the stability of isobutenyl radicals" @default.
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- W2076135636 doi "https://doi.org/10.1002/kin.550050604" @default.
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