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- W2076136980 abstract "Interesting norbornane-fused tetrahydrofurans, with an additional synthetically-valuable vicinal dioxy-substitution in the norbornane skeleton, are enantiospecifically obtained in high yield from epimeric camphor-derived 3-endo-bromomethyl-substituted spiroepoxidic 1-norbornyl triflates. The process takes place via a domino reaction stereoelectronically controlled by the bromine atom. The described process has synthetic value, since it opens the way for a future enantiospecific preparation of 2,3-disubstituted tetrahydrofurans from camphor." @default.
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- W2076136980 date "2011-04-01" @default.
- W2076136980 modified "2023-10-16" @default.
- W2076136980 title "Stereoelectronic control in the solvolysis of spiroepoxidic 1-norbornyl triflates: unexpected reactivity in 3-bromomethyl derivatives" @default.
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- W2076136980 doi "https://doi.org/10.1016/j.tetlet.2011.02.006" @default.
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